The purpose of this experiment is to analyze the P content in a wastewater sample and to test the efficiency of 2 different methods for P removal from wastewater.
To analyze the P content in a wastewater sample, standard P solution is made and calibration curve is generated and phosphate concentration in wastewater is determined by using calibration curve that is generated. To determine the concentration of P, vanadomolybdophosphoric acid spectrophotometric method is used. The predominating form of phosphate is dependent on pH.
H₃PO₄ ⇌ H₂PO₄⁻ + H⁺ pKₐ=2.12
H₂PO₄⁻ ⇌ HPO₄²⁻ + H⁺ pKₐ=7.25
HPO₄²⁻ ⇌ PO₄³⁻ + H⁺ pKₐ=12.7
This method is under the acidic condition and ammonium molybdate is reacted with phosphate, then, the product reacts
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By adding theoretical dose of alum which was 6.55mg of alum, 4.9% of phosphate was removed. However, by adding pragmatic dose of alum which was 20mg of alum, 86% of phosphate was removed. This was because that the equilibrium the equation,
Al³⁺ + HₐPO₄³⁻ ͣ ⇌ AlPO₄ + aH⁺ showed that when excess Al³⁺ was added, then the reaction went forward which would make more products of AlPO₄ + aH⁺. Therefore, by adding pragmatic dose of alum of 200mg/L produced more precipitate of AlPO₄ which was the way of removing phosphorus so this was more effective than by adding theoretical dose of alum.
Answers
2 main hazards were acidified vanadate-molybdate reagent and sodium hydroxide. Especially for handling the acidified vanadate-molybdate reagent, the gloves and safety glasses must be worn and it has to be used in fume hood. For NaOH, must be careful when handling so that it does not spill. If there is a spillage, contaminated clothes should be removed, and rinse eyes, skin, clothes and equipment with lots of water and also must report supervisor.
H₂PO₄⁻, HPO₄²⁻ present in pH of 7.25.
M(H₂PO₄⁻) = 97g/mol
0.1/ 97 = 1.03x10⁻³mol/L
1.03x10⁻³ x 31 = 0.0319 =
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When pH is high which means more OH⁻, then aluminum ions will react with hydroxide ions to form aluminum hydroxide. Phosphate ions are acting as a natural buffer.
If the equipment is not washed with acid, it would cause an error. This is because the phosphorus analyzing is dealing with low concentration of phosphorus and it is easily contaminated by detergent and other chemicals and it has to be washed by using an acid and also it has to be rinsed with distilled water once it is rinsed with acid. Also refer to section 4 (discussion).
Calcium phosphate is found in teeth and bones.
Alum is used for the sedimentation tank in water treatment places because alum addition leads to flocculate the charged colloidal particles.
For alum-precipitation, the aluminum phosphate from the wastewater would have bacteria and viruses. When phosphate from wastewater is used, the main problem is that there will be microbiological hazards so the plants and animals can be contaminated from that alum-precipitation.
One person generates 150L of wastewater, 500 habitants in Rongotea and each 1L; it needs 200mg of
The purpose of the lab is to acquire the percent composition of zinc and copper. The procedure included obtaining a post 1983 penny and washing it with soap and water. Using a triangular file, we made an X on the penny. Then, we cleaned the top and bottom of the penny with steel wool until it was shiny. We rinsed the penny in acetone and dried it with paper towel.
Marwah Alabbad Post lab 10/21/15 Question 1: 1. Experiment 1: Number of trails NaOH concentration (M) Volume of HCl solution (mL) Initial volume of NaOH(mL) final volume of NaOH(mL) The volume of NaOH to titrate HCl (mL) Concentration of HCl (M) 1st 0.1023 25.0 10.05 36.12 26.07 0.085 2nd 0.1023 25.0 5.74 31.40 25.66 0.105 3rd 0.1023 25.0 9.84 35.52 25.68 0.105 First trail calculation: 0.02607L× (0.1023mole NaOH/1L)×(1 mol of HCL/1 mol of NaOH)×(1/0.025)= 0.085M of HCl
The purpose of this experiment was to analyze the % phosphorous in Miracle Gro. Gravimetric Analysis was used to determine the content of phosphorous in this water soluble fertilizer. The overall goal of Gravimetric Analysis is to form the precipitate MgNH4PO46H2O and isolate it from the aqueous solution by vacuum filtration. In order to obtain the precipitate, a series of dissolution reactions and vacuum filtration were performed. First, Miracle Gro was dissolved with DI water and reacted with activated copper to remove coppers ions in the fertilizer.
This week we went to the Conodoguinet Creek. While we were at the creek we did many different things. One of the experiments we did was the Critter Count which was my favorite. Another experiment we did was the Eutrophication Tests. The last Experiment we did was the bobber test.
In this lab we were trying to figure out if Salt Creek and Barker Lake had the correct chemical balances to sustain catfish for the years coming. In order to find this out, we tested the water using a Hach Water Testing Kit. Inside were dissolved oxygen reagent powder pillows 1, 2 and 3 which we added and mixed into our sample water to prepare it for testing. Then we added droplets of Sodium Thiosulphate Solution into the prepared water too see how much dissolved oxygen parts per million were in the water. Our independent variable in this experiment was the 5 different testing sites that we went to for water samples.
1. Identify the range of senses involved in communication • Sight (visual communication), Touch (tactile communication), Taste, Hearing (auditory communication), Smell (olfactory communication) 2. Identify the limited range of wavelengths and named parts of the electromagnetic spectrum detected by humans and compare this range with those of THREE other named vertebrates and TWO named invertebrates. Figure 1: the electromagnetic spectrum source: www.ces.fau.edu Vertebrates Human Japanese Dace Fish Rattlesnake Zebra Finch Part of electromagnetic spectrum detected ROYGBV (visible light) detected by light sensitive cells in the eye called rods and cones.
The lab started off by measuring critical materials for the lab: the mass of an an empty 100 mL beaker, mass of beaker and copper chloride together(52.30 g), and the mass of three iron nails(2.73 g). The goal of this experiment is to determine the number of moles of copper and iron that would be produced in the reaction of iron and copper(II) chloride, the ratio of moles of iron to moles of copper, and the percent yield of copper produced. 2.00 grams of copper(II) chloride was added in the beaker to mix with 15 mL of distilled water. Then, three dry nails are placed in the copper(II) chloride solution for approximately 25 minutes. The three nails have to be scraped clean by sandpaper to make the surface of the nail shiny; if the nails are not clean, then some unknown substances might accidentally mix into the reaction and cause variations of the result.
Tn 4351 was originally isolated from bacteroides fragilis [30] . The transposon was successfully introduced into Cytophaga succinicans, Flavobacterium meningosepticum, Flexibacter canadiansis, Flexibacter strain SFI and Sporocytophaga myxococcoides by conjugation [25]. Tn 4351carries two antibiotic resistance gene. One of the codes for resistance to erythromycin and clindamycin which is expressed in bactroides but not in E.Coli. The other gene codes for resistance in tetracycline and is expressed in aerobically grpwn E. coli, but not in anaerobically grpwn E. coli or in bacteroides.
This has been a major contributor to the massive loss of life in the Chesapeake Bay waters. The average of phosphate tests were approximately zero and one tenth ppm (parts per million.) The lower the phosphate number, the smaller amount of pollution there is in the water. The average amount of nitrate in the water was approximately zero and nine tenths. The same scenario as the phosphate, the lower the number, the smaller amount of pollution.
CLAIRE MUNTING 29/01/2018 Criterion C EFFECTS OF SURFACE AREA OF CALCIUM CARBONATE UPON RATE OF REACTION Calcium Carbonate Chips 1 Introduction: Within the current investigation, the effects of the surface area of Calcium Carbonate (CaCO3) in combination with Hydrochloric acid (HCl) upon its rate of reaction. CaCO3, commonly referred to as limestone, is an organic substance and is, in a sense, the crystallised “carbonic salt” of the element, calcium2. In addition to being a salt, the pH level of Calcium Carbonate is 9.91, and it is therefore, a basic substance, due to the fact that it is comprised of a pH level higher than 7, which is neutral3. HCl, however, is the bodily acid found in the stomach of human beings.
Verna Wang Hannah Palmer CHEM 101-069 Lab 11-19-16 Stoichiometry and Limiting Reagents Lab Report Purpose: We are using the reaction of sodium hydroxide and calcium chloride to illustrate stoichiometry by demonstrating proportions needed to cause a reaction to take place. Background: Just like a recipe would call for a specific amount of one ingredient to a specific amount of another, stoichiometry is the same exact method for calculating moles in a chemical reaction. Sometimes, we may not have enough of or too much of one ingredient , which would be defined as limiting and excess reagent, respectively.
Introduction: In this task I will be researching the effect that acid rain has on the rate of plant growth. Acid rain is any type of precipitation with a high pH, with high levels of nitric acids. The reason why I had chosen this topic was because acid rain seems to have a great effect on the effect of plant growth, and plants play a very important role in our ecosystem. Acid rain is a major problem in our environment when we are not able to neutralize the acidity.
Introduction: In this lab, of water in a hydrate, or a substance whose crystalline structure is bound to water molecules by weak bonds, is determined by heating up a small sample of it. By heating, the water of hydration, or bound water, is removed, leaving only what is called an anhydrous compound. Based on the percent water in the hydrate, it can be classified as one of three types: BaCl2O ⋅ 2H20, with a percent water of about 14.57%, CuSO4
Biochemical tests are the tests used for the identification of bacterial species based on the differences in the biochemical activities of different bacteria. Bacterial physiology differs from one species to the other. These differences in carbohydrate metabolism, protein metabolism, fat metabolism, production of certain enzymes and ability to utilize a particular compound help them to be identified by the biochemical tests. Gram’s stain was originally devised by histologist Hans Christian Gram in 1884. Gram-positive bacteria stain purple, while Gram-negative bacteria stain pink when subjected to Gram staining.
The NaH2PO4 and Na2HPO4 powdered were weighted by using weighing machine, followed the mass that has been calculated in step (3). The NaH2PO4 and Na2HPO4 powdered were mix in a 500 mL beaker. 500 mL of distilled water were measured by using a 500 mL measuring cylinder, then is poured inside the 500 mL beaker containing both the powdered.