Valenzuela et. al. (1995) [100] has proposed a hydrometallurgical procedure for the separation of molybdenum from Chilean molybdenite concentrate. The molybdenite concentrate was first leached with nitric acid originated from the reaction of NaNO3 and H2SO4, which provided a solid phase, composed of MoO3 and residual solution. Molybdenum was separated with alkylphosphonic acid PC-88A by solvent extraction method, from the leach liquor containing copper, rhenium and iron among other impurities. The extraction efficiency of molybdenum was about 96% at pH 0.8 with zero co-extraction of other metals. The loaded organic was stripped with ammonia aqueous solution. One extraction stage and two stripping stages were required for the enrichment of Mo …show more content…
al. (1998) [103] preferred DIDA over wildly known amine extractant TOA, due to its possibility of using as extractant without adding a modifier. The parameters of solvent extraction such as aqueous phase acidity, type of diluents, molybdenum concentration, and DIDA concentration were investigated to obtain the suitable condition for effective extraction of molybdenum. The extraction mechanism was an anion-exchange reaction, which formed a polymeric complex, expressed as (R2NH)n MomOp(HSO4)y, where the values of n, m, p and y are depend on the polymerization degrees of molybdenum and amine in organic and aqueous phase. The polymeric complex changes according to the concentration of DIDA and metal, aqueous acidity, diluents, time, and type of extraction process. The extraction of molybdenum was sensitive to diluents and it decreased in the order of toluene> kerosene>EDD-1. Caiozzi M et al. (1969) [104] have used tributyl phosphate (TBP) for the extraction of peroxymolybdate complex from sulphate medium. The effect of solvent extraction parameters was examined and the extraction behaviour of other ions was studied. The developed analytical procedure for molybdenum determination was used for ore …show more content…
The extraction efficiency was most successful with dichloroethane as diluents than any others. Stripping study was carried out with hydrochloric acid. The method was applied for the separation of Mo from minerals composed of different kinds of metals. In this experiment molybdenum was determined by drywashing it and was followed by spectrophotometrically analysis as a complex with Tiron at 390 nm. Turel and Patil (1996) [112] have established a rapid and selective method for the extraction of molybdenum with malachite green into nitrobenzene. The influence of solvent extraction variables on molybdenum extraction such as effect of pH, time of equilibration, solvents, effect of various anions and cations have been studied. On the basis of substoichiometric extraction method the constituent ratio of the metal-organic complexes was found as 1:1. The slope ratio method was also in agreement with the
Cadet Eric Wiggins Date: 18 September 2014 Course Name: Chem 100 Instructor: Captain Zuniga Section: M3A Identification of a Copper Mineral Intro Minerals are elements or compounds that are created in the Earth by geological processes. The method of isolating metals in a compound mineral is normally conducted through two processes.
K.D.A. Saboia et al. , (2007) have been prepared the Bi4Ti3O12–CaCu3Ti4O12 {[BIT(X)–CCTO(100-X)]} composite powders through solid state reaction method and calcined in the range of 900 to 1020 ºC for 12 h. The as-prepared powders have modified in the form of thick film onto alumina ceramic substrate by utilizing screen printing. At 100 Hz, the value of dielectric constant (κ) of CCTO100 and BIT100 is 316.61 and 53.64 respectively. Conversely, the composite with X=20 % shows an unexpected dielectric constant of 409.71, which is around 20% higher in comparison with the CCTO.
Metal cations can be identified based on the colors they emitted off when heated in a flame.1 When atoms of the ions that were tested are excited, their electrons move up to higher levels of energy.2 When the electrons relax and return to the original states, they emit photons of specific energy creating wavelengths of light that produces colors.3 The test wire and Bunsen Burner were used to excite the solution in the crucible. The standard metal cations that were tested and their outcomes are as shown in Table 1.
The hypothesis was supported by the employed methods. Introduction: This experiment was performed to show how bromination of alkenes reacts, and to be able to successfully synthesize meso-stilbene dibromide. The reaction of bromine with alkenes is an addition reaction where the nucleophilic double bond attacks the electrophilic bromine
If the ion is in solution, NaOH can be added and if a blue precipitate is formed the metal ion is copper (1). A flame test can also be used to identify the metal ion. Copper burns blue-green (1) and iron burns gold (3). A quantitative test can be used to then determine the charge of the metal ion.
From the AA spectrometer’s readings (conducted by Dr. Stephanie Le Clair), the absorbance was calculated for the Ca2+ and Mg2+ which were dissolved in the sample connected to the spectrometer through a tube. Following testing, graphs of light absorbance versus metal ion concentration were created, and the obtained equations from the trend line were used to translate the values into the corresponding concentration of CaCO3 (see
The lab started off by measuring critical materials for the lab: the mass of an an empty 100 mL beaker, mass of beaker and copper chloride together(52.30 g), and the mass of three iron nails(2.73 g). The goal of this experiment is to determine the number of moles of copper and iron that would be produced in the reaction of iron and copper(II) chloride, the ratio of moles of iron to moles of copper, and the percent yield of copper produced. 2.00 grams of copper(II) chloride was added in the beaker to mix with 15 mL of distilled water. Then, three dry nails are placed in the copper(II) chloride solution for approximately 25 minutes. The three nails have to be scraped clean by sandpaper to make the surface of the nail shiny; if the nails are not clean, then some unknown substances might accidentally mix into the reaction and cause variations of the result.
But the source of this manganese is not known. Manganese is also found in Wad. It's of little economic importance bc it's hard economic value when separation occurs. Manganese is also found in the mineral manganite.
Lab 27. Stoichiometry and Chemical Reactions Report In our lab we were asked Which Balanced Chemical Equation Best Represents the Thermal Decomposition of Sodium Bicarbonate. Sodium Bicarbonate is a chemical compound with the formula NaHCO3, also known as baking soda. In the process to answer our guiding question we have to determine how atoms are rearranged during a chemical reaction.
In this lab, three unknown compounds were separated from a mixture and identified by melting point. Unknown mixture #124 has components of acid, base and neutral compound. The compounds were identified by melting point and matched up with the known melting points from a given list. In order to identify the compound it was important to separate by dissolving the mixture in an organic solvent which was not soluble in water, and then extracting the solution first with HCl, and then dilute sodium hydroxide solution. From the separation mixture, the aqueous layer were obtained and labeled as TT-1 (base), TT-2(acid) and TT-3 (neutral) in three different test tubes for later recovery.
This was achieved by using physical observations, logic, and mathematical calculations. In order to do this efficiently, several answer choices were given for the unknown metals. These choices were Bismuth, Manganese, Copper, Lead, Zinc, Tin, Cobalt, Nickel, Cadmium, and Chromium. For the unknown metal in this case (sample #21), the density was approximately 6.848g/cm3. This alone however, is not enough information to identify the metal.
Chem 51LB Report Ngoc Tran - Student ID # 72048507 The purpose of this lab is to examine the composition of three components of gas products of elimination reaction under acidic condition by conducting the dehydration of primary and secondary alcohol, and under basic condition by conducting the base-induced dehydrobromination of 1-bromobutane and 2-bromobutane. Then gas chromatography is used to analyze the composition of the product mixtures. Gas chromatography (mobile phase) is used to analyze the composition of three components of the gas products. A syringe needle with gas product is injected into the machine, and the component is eluted and the composition is related to the column or the peaks.
Nonetheless, the light yellow solid was purified by using the recrystallization technique. The formation of o-nitroacetanilide is inevitable and in order to eliminate it, 95% ethanol is used as the solvent of choice. The ortho isomer is soluble in the cold alcohol solution whereas p-nitroacetanilide in insoluble. As a result, the ortho isomer remains in the liquid solution and the final product, the p-nitroacetanilide is isolated with a final vacuum
I. Purpose: To experimentally determine the mass and the mole content of a measured sample. II. Materials: The materials used in this experiment a 50-mL beaker, 12 samples, a balance and paper towels. III.
Nevertheless, the latter is not used in this experiment since it is very reactive and extremely flammable. On the contrary, NaBH4 is relatively mild and it can be used with protic solvents. In this manner, 1.507 grs of the ketone 9-fluorenone were mixed with 30.0 ml of 95% ethanol in a 125 ml Erlenmeyer flask. The bright yellow mixture was stirred during 7 minutes until all the components were dissolved.